tailieunhanh - Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-phthalocyanines: Synthesis, characterization, and investigation of their electrochemical, photochemical and computational properties

The current study describes the synthesis, electrochemical, computational, and photochemical properties of octa (3-hydroxypropylthio) substituted cobalt (II) (4), copper (II) (5), nickel (II) (6) and zinc(II) (7) phthalocyanine derivatives. These novel compounds were characterized by elemental analysis, 1H, 13C NMR, FT-IR, UV-Vis, and MS. The redox behaviors of these metallophthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital (GIAO) 1H and 13C NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP/6–31G(d,p) basis set. | Turkish Journal of Chemistry Turk J Chem 2021 45 143-156 http chem TÜBİTAK Research Article doi kim-2008-48 Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-phthalocyanines synthesis characterization and investigation of their electrochemical photochemical and computational properties 1 2 3 4 5 5 6 Nilgün KABAY Yasemin BAYGU Metin AK İzzet KARA EsraNur KAYA Mahmut DURMUŞ Yaşar GÖK 1 Department of Biomedical Engineering Pamukkale University Denizli Turkey 2 Tavas Vocational School of Higher Education Pamukkale University Denizli Turkey 3 Department of Chemistry Pamukkale University Denizli Turkey 4 Department of Physical Education Pamukkale University Denizli Turkey 5 Department of Chemistry Gebze Technical University Kocaeli Turkey 6 Department of Chemical Engineering Uşak University Uşak Turkey Received Accepted Published Online Final Version Abstract The current study describes the synthesis electrochemical computational and photochemical properties of octa 3-hydroxypropylthio substituted cobalt II 4 copper II 5 nickel II 6 and zinc II 7 phthalocyanine derivatives. These novel compounds were characterized by elemental analysis 1H 13C NMR FT-IR UV-Vis and MS. The redox behaviors of these metallo- phthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital GIAO 1H and 13C NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP 6 31G d p basis set. The outcomes of the optimized molecular structure were given and compared with the experimental NMR values. The photochemical properties including photodegradation and singlet oxygen generation of zinc II phthalocyanine were studied in DMSO solution for the determination of its photosensitizer behaviors. Key words Metallo-phthalocyanines cyclic voltammetry computational chemistry photodynamic therapy photochemical .

• Hoá học
• Journal of Chemistry
• Metallo phthalocyanines
• Cyclic voltammetry
• Computational chemistry
• Photodynamic therapy
• Photochemical properties
• Journal of technology and science education
• Innovative chemistry learning model
• Improving the critical thinking skill
• Self efficacy of pre service chemistry teachers
• Pre service chemistry teachers
• SCT learning model syntax covers
• The Chemistry and Antimicrobial Activity of Psychotria reevesii Wall
• The Chemistry and Antimicrobial Activity
• Psychotria reevesii Wall
• The polar fractions against Staphylococcus aureus
• The relationship between teacher related factors
• Students attitudes towards secondary school chemistry subject
• Bureti district Kenya
• Secondary school chemistry subject
• Click chemistry
• Poly(ethylene glycol)
• Poly(epsilon caprolactone)
• Azide functionalized molecules
• Azide montmorillonite clay
• Block copolymer
• Ketene chemistry
• Telechelic polymers
• Controlled radical polymerization (CRP)
• C60 fullerene
• Metallosupramolecular chemistry
• Host–guest complexes
• Supramolecular chemistry
• Donor–acceptor (D–A)
• Ring opening polymerization
• Thiol benzoxazine reaction
• Catechol based benzoxazine copolymer
• Antibacterial coatings
• Benzoxazine chemistry
• Green chemistry
• Heavy metals
• Cetylpyridinium chloride
• Analytical chemistry
• Journal of Science and Technology
• Green organic synthesis of N methylpyrrolidine
• Gas Chromatography Mass spectroscopy
• The green chemistry process
• Via the green chemistry process
• Journal of medical research
• Production of liophilized quality control samples
• Liophilized quality control samples
• Several clinical chemistry test
• Statistical quality control
• Perspectives on blended learning
• The on line platform
• LabLessons for Chemistry
• Hydrogen and Titration
• College mentors alongside
• Contextualizing technology in the classroom via remote access
• Using space exploration themes
• Scanning electron microscopy
• Tools to promote engagement
• Multidisciplinary geology chemistry experiments
• The service of learning chemistry in Industrial Engineering
• Degrees in Industrial Engineering
• Chemical Engineering and Materials Engineering
• The feed back
• Assessment of achievement in problem solving skills
• General Chemistry course
• Problem based learning
• Measure problem solving skills
• Use of chemistry software to teach
• Assess model based reaction and equation knowledge
• Assess model based reaction
• Two advanced placement
• Public suburban high school
• Collaborative activities for solving multi step problems
• Solving multi step problems in general chemistry
• Solving multi step problems
• The relatve partcipaton of instructor students
• Antioxidant activity
• Bioinorganic chemistry
• Cytotoxic activity
• DNA binding and cleavage activity
• Topoisomerase inhibitor
• Transition metal compounds
• Analytical methods
• Electroanalytical chemistry
• Ionic liquids
• Penicillin allergic patients
• Capillary electrophoresis
• Carbamate SCC interactions
• Fluorescence quenching
• Quantum chemistry calculation
• Inhibition chemiluminescence
• Piperazine chemistry
• Structural features
• Anticancer activity
• Anticancer drugs
• D cyclin dependent kinase
• 3 Amino 9 ethylcarbazole
• Multicomponent reaction
• Arylation reactions
• Cyclization reactions
• Pyrrolo[2 3 c]carbazole
• Prido[3 2 b]carbazole
• Ionic liquid
• Organic phase change materials
• Thermal energy storage
• Solvent free medium
• Silicon chemistry
• Reaction mechanism
• Density functional theory (DFT)
• Homogeneous transitionmetal catalysis
• Silicon analogues
• Medicinal chemistry
• Antiproliferative agents
• Protect endangered tissue
• Anti inflammatory cytokines
• Persistent inflammatory reaction
• Formic acid decomposition
• Renewable feedstock
• Energy feedstocks
• High surface area materials