tailieunhanh - The Glauber reaction to manufacture potassium permanganate: An optimal balance between commercial efficiency and sustainability

In this minireview, the efficiency of the Glauber reaction was evaluated by equilibrium determinations and comparatively viewed in light of today’s principle of sustainability. The manufacture of potassium permanganate through the method based on the Glauber reaction is taking a step in the direction of building a more sustainable world. | Cite this paper Vietnam J. Chem. 2023 61 S1 86-88 Minireview DOI The Glauber reaction to manufacture potassium permanganate An optimal balance between commercial efficiency and sustainability Aliyar Mousavi Math amp Sciences Department Nashua Community College 505 Amherst Street Nashua NH 03063 . Submitted April 12 2023 Revised May 10 2023 Accepted May 15 2023 Abstract The spontaneous oxidation of aqueous potassium manganate to aqueous potassium permanganate first carried out by the German alchemist of the 17th century Johann Rudolf Glauber was used for the manufacture of potassium permanganate until it was replaced with the electrolytic oxidation of potassium manganate which is the current state of the art. The reason for the replacement was that the method that is based on the Glauber reaction is commercially less efficient. In this minireview the efficiency of the Glauber reaction was evaluated by equilibrium determinations and comparatively viewed in light of today s principle of sustainability. The manufacture of potassium permanganate through the method based on the Glauber reaction is taking a step in the direction of building a more sustainable world. Keywords. Disproportionation Glauber manganate permanganate sustainable development. Pyrolusite manganese dioxide MnO2 is the most disproportionation of the alkaline K2MnO4 induced common of the commercially more important by reducing the pH with carbon dioxide CO2 . deposits of manganese. 1 The German alchemist of However the method has been replaced with the the 17th century Johann Rudolf Glauber 2 made that electrolytic oxidation of K2MnO4 according to the mineral undergo oxidation and prepared an aqueous reaction shown by Equation 2. 1 solution of potassium manganate K2MnO4 . 3 The 2K2MnO4 aq 2H2O l 2KMnO4 aq green solution however changed color slowly 3 as 2KOH aq H2 g 2 the very dark-green K2MnO4 was oxidized to the The method that is based on the Glauber reaction deep-purple