tailieunhanh - Tribological behavior and quantum chemical calculations of protic ionic liquids: synthesis, spectroscopic, and thermal properties

Protic ionic liquids (PILs) were synthesized through a stoichiometric neutralization reaction between 2,2′ - (ethylenedioxy)-bis(ethylamine) { Edbea} and various acids (formic, acetic, boric, decanoic, and gentisic acid). The PILs were characterized by elemental analyses, FTIR, 1 H and 13 C NMR spectroscopy, and thermogravimetric analysis. All the PILs except PIL3 were liquid at room temperature. The viscosity of the PILs (PIL1, 2, 4, 5) was measured using a cone-and-plate viscometer at ambient temperature. Quantum chemical calculations were used to explain the cation/anion ratio in the PILs. |

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