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Spectrophotometric analysis of stability of gold nanoparticles during catalytic reduction of 4-nitrophenol

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Spectrophotometric monitoring of 4-nitrophenol (4-NP) reduction by sodium borohydride (NaBH4 ) using gold nanoparticles (GNPs) as a catalyst has been extensively studied, but the stability of GNPs in terms of change in the surface plasmon resonance (SPR) at different temperatures has not been explored. In the present investigation, our aim was to evaluate the SPR stability of GNPs as a catalyst during the reduction of 4-NP at different elevated temperatures (i.e. 30–60 °C) and sodium borohydride concentrations. Sensitivity of this degradation process toward concentration of GNPs at a range of temperatures is also evaluated. |