tailieunhanh - Branched Polymers I Episode 3

Tham khảo tài liệu 'branched polymers i episode 3', kỹ thuật - công nghệ, cơ khí - chế tạo máy phục vụ nhu cầu học tập, nghiên cứu và làm việc hiệu quả | Poly macromonomers Homo- and Copolymerization Koichi Ito1 Seigou Kawaguchi Department of Materials Science Toyohashi University of Technology Tempaku-cho Toyohashi 441-8580 Japan 1 E-mail itoh@ Syntheses and characterization of branched polymers prepared by homo- and copolymerization of macromonomers are reviewed. A number of macromonomers have so far been available as potential building blocks to design a variety of well-defined branched homo-and copolymers including comb star brush and graft types. Recent progress in macromonomer syntheses macromonomers homo- and copolymerization characterization of the branched polymers obtained as well as application to design of polymeric microspheres are described. Macromonomers and their homo- and copolymerization appear to provide continuing interest in designing and characterizing a variety of branched polymers and in their unique applications. Keywords. Poly macromonomers Graft copolymers Comb Star Brush Polymeric microspheres List of Symbols and Abbreviations. 130 1 Introduction. 133 2 Survey of Macromonomer Techniques . 134 3 Syntheses of Macromonomers. 136 Polyolefins. 136 Polystyrenes. 137 Polyacrylates. 139 Poly ethylene oxide . 139 Some Other New Macromonomers. 141 4 Homopolymerization and Copolymerization of Macromonomers. 141 Homopolymerization. 142 Copolymerization . 145 5 Characterization of Star and Comb Polymers. 148 Characterization and Solution Properties of Poly macromonomers . 149 Advances in Polymer Science Springer-Verlag Berlin Heidelberg 1999 130 K. Ito S. Kawaguchi Bulk Some Properties of Graft 6 Design of Polymeric Microspheres Using Dispersion Mechanistic Model of Dispersion Copolymerization with Emulsion Chain Conformation of Grafted Polymer Chains at Interfaces . . . .171 7 Conclusions and 8 References .174

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