tailieunhanh - Electrochemistry of Fe(IV) and Mn(IV) corroles containing meso-dichlorophenyl substituents and the use of these compounds as catalysts for the electroreduction of dioxygen in acid media

Two meso-dichlorophenyl substituted metallocorroles were synthesized and characterized as to their electrochemical and spectroelectrochemical properties in dichloromethane, benzonitrile, and pyridine containing M tetra-n-butylammonium perchlorate (TBAP) as supporting electrolyte. The examined compounds are represented as (Cl2Ph)3 CorFeIVCl and (Cl2Ph)3 CorMnIVCl where (Cl2Ph)3 Cor is the trianion of 5,10,15-tri(2,4-dichlorophenyl)corrole. Each metallocorrole was examined as to its catalytic activity for the electoreduction of dioxygen when coated on an edge-plane pyrolytic graphite electrode in M HClO4. |

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