tailieunhanh - Cost-effective porous carbon materials synthesized by carbonizing rice husk and K2CO3 activation and their application for lithium-sulfur batteries

In this work, we developed highly porous activated carbon (AC) materials with micro/meso porosity through carbonizing rice husk and treating them with K2CO3. Elemental sulfur was then loaded to the micropores through a solution infiltration method to form rice husk-derived activated carbon (RHAC)aS composite materials. | Journal of Science Advanced Materials and Devices 4 2019 223e229 Contents lists available at ScienceDirect Journal of Science Advanced Materials and Devices journal homepage locate jsamd Original Article Cost-effective porous carbon materials synthesized by carbonizing rice husk and K2CO3 activation and their application for lithium-sulfur batteries Thanh-Tung Mai a Duc-Luong Vu a Dang- Chinh Huynh a Nae-Li Wu b Anh-Tuan Le c d a School of Chemical Engineering Hanoi University of Science and Technology Ha Noi Viet Nam b Department of Chemical Engineering National Taiwan University Taipei 106 Taiwan c Phenikaa University Nano Institute PHENA Phenikaa University Hanoi 12116 Viet Nam d Faculty of Materials Science and Engineering Phenikaa University Hanoi 12116 Viet Nam a r t i c l e i n f o a b s t r a c t Article history In this work we developed highly porous activated carbon AC materials with micro meso porosity Received 18 March 2019 through carbonizing rice husk and treating them with K2CO3. Elemental sulfur was then loaded to the Received in revised form micropores through a solution infiltration method to form rice husk-derived activated carbon RHAC @S 25 April 2019 composite materials. The as-prepared RHAC@S composites with mg cm 1 and mg cm 1 of Accepted 25 April 2019 Available online 30 April 2019 sulfur loading were tested as cathodes for lithium-sulfur Li-S batteries. The mg cm 1 sulfur loaded sample showed an initial discharge capacity of 1080 mA h g at a C rate. After 50 cycles of charge discharge tests at the current density of C the reversible capacity is maintained at 312 mA h g. The Keywords Rice husk RHAC material delivered a capacity of more than 300 mA h g at a current density of C. These results Cathode material demonstrate that the RHAC porous materials are very promising as cathode materials for the develop- Carbonization process ment of high-performance Li-S batteries. Activated carbon 2019 The .

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