tailieunhanh - DNA-binding, catalytic oxidation, CAC coupling reactions and antibacterial activities of binuclear Ru(II) thiosemicarbazone complexes: Synthesis and spectral characterization

New hexa-coordinated binuclear Ru(II) thiosemicarbazone complexes of the type {[(B)(EPh3)(CO)ClRu]2L} (where, E = P or As; B = PPh3 or AsPh3 or pyridine; L = mononucleating NS donor of N-substituted thiosemicarbazones) have been synthesized and characterized by elemental analysis, FT-IR, UV–vis and 31P{1 H} NMR cyclic voltammetric studies. The DNA-binding studies of Ru(II) complexes with calf thymus DNA (CT-DNA) were investigated by UV–vis, viscosity measurements, gel-electrophoresis and fluorescence spectroscopy. The new complexes have been used as catalysts in CAC coupling reaction and in the oxidation of alcohols to their corresponding carbonyl compounds by using NMO as co-oxidant and molecular oxygen (O2) atmosphere at ambient temperature. Further, the new binucleating thiosemicarbazone ligands and their Ru(II) complexes were also screened for their antibacterial activity against Klebsiella pneumoniae, Shigella sp., Micrococcus luteus, Escherichia coli and Salmonella typhi. | DNA-binding, catalytic oxidation, CAC coupling reactions and antibacterial activities of binuclear Ru(II) thiosemicarbazone complexes: Synthesis and spectral characterization

• Sinh học
• Binuclear ruthenium(II)
• CT DNA
• Catalytic reactions
• Antibacterial activity
• Spectral characterization
• Natural science
• Isoeugenoxyacetic acid
• Hydrazones derived
• Aromatic aldehydes
• Journal of Chemistry
• FT IR spectral foundations
• Silico chemoinformatic
• Antimicrobial drugs
• Cytotoxic activity
• Synthesis and characterization
• Fluoroaniline Schiff bases
• In vitro antibacterial activity
• FT IR spectral studies
• Methicillin resistant Staphylococcus aureus
• báo cáo của tạp chí Journal of Operator Theory
• tài liệu báo cáo nghiên cứu khoa học
• cách trình bày báo cáo
• kiến thức toán học
• báo cáo toán học
• báo cáo hóa học
• công trình nghiên cứu về hóa học
• tài liệu về hóa học
• công trình toán học
• các báo cáo toán học hay
• Thiadiazolo[3
• 2 a]pyrimidine
• RHF ab initio calculations
• Annulated ring junction pyrimidine derivatives
• Ab initio calculations
• Elemental analysis and spectral data
• BMC Chemistry
• Single crystal X ray
• Molecular docking
• Staphylococcus aureus bacterial
• DNA cleavage studies
• 1 3 4 Thiadiazol 2 amines
• Useful synthetic drugs
• DNA binding interactions
• Absorption and fluorescence spectroscopy
• Docking studies
• Analyzed by spectral analysis
• P TSA catalyzed synthesis
• Ethyl 3 methoxyquinoxaline 2 carboxylate
• Free energy of binding
• Phthalhydrazidylazo derivative
• Unsaturated diketone
• Keto hydrazone
• Metal complexes
• Spectral data
• Fluorescent studies
• Coordination polymer
• Spectral studies
• Thermogravimetric analysis (TGA)
• Biological activity
• Phthalocyanine derivatives
• 2 {[2(dimethylamino)ethyl] methylamino} ethanol
• Water soluble
• UV Vis spectral data
• Quantum yields
• Singlet oxygen
• Thin film
• X ray diffraction spectroscopy
• Crystalline CoPc
• Vic dioxime
• Spectral analysis
• X ray diffraction
• Antifungal activity
• Nuclear engineering and technology
• Neutron and gamma ray energy reconstruction
• Characterization of special nuclear material
• Special nuclear material
• Gamma ray sources
• The reference spectral
• Fluorescent probes
• Cell imaging
• Ethanol–water solution
• pH dependent spectrum
• UV vis spectral response