tailieunhanh - Chapter 1: ISOMERISM

Isomers: Compounds with the same molecular formula but different structural formulas. Different compounds that have the same molecular formula – but differ in their connectivity. Isomers that differ in the way their atoms are arranged in space | ORGANIC CHEMISTRY Dr Nam T. S. Phan Faculty of Chemical Engineering HCMC University of Technology Office: room 211, B2 Building Phone: 8647256 ext. 5681 Email: ptsnam@ REFERENCES [1] Nam T. S. Phan, Hoa T. V. Tran ‘Organic chemistry’, VNU-HCMC Publisher, 2010 [2] Nam T. S. Phan, ‘Study guide to organic chemistry’, VNU-HCMC Publisher, 2009 [3] Paula Y. Bruice, ‘Organic chemistry’, fifth edition, Pearson Prentice Hall, 2007 [4] Francis A. Carey, ‘Organic chemistry’, fifth edition, McGraw-Hill, 2003 [5] Paula Y. Bruice, ‘Study guide and solutions manual - Organic chemistry’, fifth edition, Pearson Prentice Hall, 2007 [6] Graham . Solomons, Craig B. Fryhle, ‘Organic chemistry’, eighth edition, John Wiley & Sons, 2004 COURSE OUTLINE Isomerism Electronic & steric effects Common reaction mechanisms Alkanes Alkenes Alkadienes Alkynes Aromatic hydrocarbons Alkyl halides Alcohols & phenols Aldehydes & ketones Carboxylic acids Amines & diazoniums Chapter 1: ISOMERISM . | ORGANIC CHEMISTRY Dr Nam T. S. Phan Faculty of Chemical Engineering HCMC University of Technology Office: room 211, B2 Building Phone: 8647256 ext. 5681 Email: ptsnam@ REFERENCES [1] Nam T. S. Phan, Hoa T. V. Tran ‘Organic chemistry’, VNU-HCMC Publisher, 2010 [2] Nam T. S. Phan, ‘Study guide to organic chemistry’, VNU-HCMC Publisher, 2009 [3] Paula Y. Bruice, ‘Organic chemistry’, fifth edition, Pearson Prentice Hall, 2007 [4] Francis A. Carey, ‘Organic chemistry’, fifth edition, McGraw-Hill, 2003 [5] Paula Y. Bruice, ‘Study guide and solutions manual - Organic chemistry’, fifth edition, Pearson Prentice Hall, 2007 [6] Graham . Solomons, Craig B. Fryhle, ‘Organic chemistry’, eighth edition, John Wiley & Sons, 2004 COURSE OUTLINE Isomerism Electronic & steric effects Common reaction mechanisms Alkanes Alkenes Alkadienes Alkynes Aromatic hydrocarbons Alkyl halides Alcohols & phenols Aldehydes & ketones Carboxylic acids Amines & diazoniums Chapter 1: ISOMERISM Isomers: Compounds with the same molecular formula but different structural formulas Constitutional isomers Conformational isomers Optical isomers /Enantiomers & Diastereoisomers Geometric isomers Configurational isomers Stereoisomers Isomers CONSTITUTIONAL ISOMERS Different compounds that have the same molecular formula – but differ in their connectivity STEREOISOMERS Isomers that differ in the way their atoms are arranged in space Conformational isomers Configurational isomers CONFORMATIONAL ISOMERS Different shapes of the same molecule resulting from rotation around a single C-C bond Conformational isomers are not different compounds Conformations of butane Conformations of cyclohexane GEOMETRIC ISOMERS There is no rotation around the C=C bond The E,Z system of nomenclature Cahn-Ingold-Prelog priority rules Rule 1 Rule 2 Rule 3 Rule 4 A chiral opbject OPTICAL ISOMERS Nonsuperimposable mirror image An achiral opbject

• Hoá học
• organic chemistry
• hóa hữu cơ
• công nghệ hóa học
• Chemical Engineering
• isomerism
• faculty of chemical engineering
• Common reaction mechanisms
• alkanes
• BMC Molecular and Cell Biology
• Cardiac stem cells
• Including right isomerism
• Cell cycle progression
• Proliferation capacities