tailieunhanh - Ebook Organic chemistry (10th edition): Part 2

(BQ) Part 2 book "Organic chemistry" has contents: Radical reactions, alcohols and ethers synthesis and reactions; alcohols from carbonyl compounds oxidation–reduction and organometallic compounds; conjugated unsaturated systems, aromatic compounds. and other contents. | 28-09-2009 15:09 Page 459 Radical Reactions 10 Unpaired electrons lead to many burning questions about radical types of reactivity. In fact, species with unpaired electrons are called radicals, and they are involved in the chemistry of burning, aging, disease, as well as in reactions related to destruction of the ozone layer and the synthesis of products that enhance our everyday lives. For example, polyethylene, which can have a molecular weight from the thousands to the millions, and practical uses ranging from plastic films and wraps to water bottles, bulletproof vests, and hip and knee replacements, is made by a reaction involving radicals. Oxygen that we breathe and nitric oxide that serves as a chemical signaling agent for some fundamental biological processes are both molecules with unpaired electrons. Highly colored natural compounds like those found in blueberries and carrots react with radicals and may protect us from undesirable biological radical reactions. Large portions of the economy hinge on radicals, as well, from reactions used to make polymers like polyethylene, to the target action of pharmaceuticals like Cialis, Levitra, and Viagra, which act on a nitric oxide biological signaling pathway. Reactions with radicals also play a role in organic synthesis. In this chapter we study the properties and reactivity of species with unpaired electrons, and we shall find that they are radically important to chemistry and life. 459 28-09-2009 460 15:09 Page 460 Chapter 10 Radical Reactions Introduction: How Radicals Form and How They React So far almost all of the reactions whose mechanisms we have studied have been ionic reactions. Ionic reactions are those in which covalent bonds break heterolytically and in which ions are involved as reactants, intermediates, or products. Another broad category of reactions has mechanisms that involve homolysis of covalent bonds with the .

• Hoá học
• Organic chemistry
• Radical reactions
• Alcohols from carbonyl compounds oxidation–reduction
• Conjugated unsaturated systems
• Cromatic compounds
• Aromatic compounds
• Rhodopseudomonas palustris
• Heterocyclic aromatic
• Morphological characteristics
• Illuminated anaerobic conditions
• 2 amino benzoic acid
• Journal of Chemistry
• Three dimensional quantitative
• Holographic quantitative structure– activity relationship
• Polycyclic aromatic hydrocarbons
• BMC Chemistry
• Catalytic hydrogenation
• Fe3O4 sub microsphere nano palladium
• Halogenated aromatic
• Nano palladium
• Reactions of aromatic compounds
• Amino acids and proteins
• Nucleic acids and protein synthesis
• Organic synthesis strategy
• Kinetic resolution
• Asymmetric synthesis
• Functionalisation of pyridine
• Oxidation of aromatic compounds
• Asymmetric induction
• Principles of organic chemistry
• Cyclic hydrocarbons
• Organic compounds
• Aromatic alcohols
• Aromatic compounds containing
• Monocyclic aromatic compounds
• Vitex negundo
• Stomach pain
• Venomous snakebite
• Anti bacterial
• Anti inflammatory
• The p o Isomer product ratios in electrophilic aromatic nitration
• Alkylbenzenes using high resolution 1 H NMR spectroscopy
• High resolution 1 H NMR spectroscopy
• Organic chemistry laboratory
• Electrophilic aromatic substitution
• Nitration of aromatic compounds
• Spectrometric identification of organic compounds
• 13C NMR spectrometry
• Functional groups containing carbon
• Heteroaromatic compounds
• Chemical shift equivalence
• Voltammetric behaviors
• Pencil graphite electrode
• Nitro substituted benzamide compounds
• Nitro aromatic compounds
• Antiinflammatory activities
• Tạp chí khoa học
• Several aromatic aldazines
• Chemical and biological
• Functional organic compounds
• Equivalent of hydrazine
• Rubstituted benzenes
• Carbonyl compounds I
• More about oxidation–reduction reactions
• Amines heterocyclic compounds
• Organophosphorous Compounds
• Solvent Information
• Aromatic Hydrocarbons
• Halogenated Hydrocarbons
• Glycol Ethers
• Petroleum Distillates
• Lecture Organic chemistry
• Hóa học hữu cơ
• Electronic Structure
• Discovery of benzene
• Organic chemistry of explosives
• Synthetic routes
• Energetic compounds
• Synthetic routes to aromatic
• Miscellaneous methods
• Organic synthesis
• The disconnection approach introduces
• Basic principles
• Amine synthesis
• General strategy
• Preparation of some new schiff bases
• Antibacterial activity
• Nitrovanillin and vanillin
• Results and Discussion
• BMC Genomics
• Zanthoxylum armatum
• De novo transcriptome
• Fatty acid
• Significantly induced
• DNA binding
• DNA photocleavage
• Photodynamic therapy
• Aromatic macrocyclic compounds
• E coli topoisomerase formulas
• Furan fused compounds
• Ammonium acetate
• Multicomponent domino reactions
• Microwave irradiation
• Aromatic aldehydes
• Catalytic oxidation
• Catalytic activity
• Gas phase
• OMS 2 material
• Anti α glucosidase
• Hemolytic activity
• Aqueous sodium carbonate
• Aromatic heterocyclic class