tailieunhanh - Ebook Modern physical organic chemistry

Ebook Modern physical organic chemistry has contents: Molecular structure and thermodynamics; reactivity, kinetics, and mechanisms; electronic structure: theory and applications. | Modern Physical Organic Chemistry Eric V. Anslyn UNIVERSITY OF TEXAS , AUSTI N Dennis A. Dougherty CALIFORNIA I NSTITUTE OF TECH NOLOGY University Science Books www. u Uni versity Science Books www. Production Manager: Christine Taylor Manuscript Editor: John Murdzek Designer: Robert Ish i Illustrator: Lineworks Compositor: Wilsted & Taylor Publishing Services Printe r & Binder: Edwards Brothers, Inc. This book is p rinted on acid-free paper. Cop yright © 2006 by University Science Books Reprodu ction or transla tion of any part o f this work beyond tha t permitted by Section 107 or 108 of the 1976 Un ited Sta tes Copyright Act w ithout the permission of the copyrigh t owner is unlawful. Requests for permission or furth er informatio n shou ld be addressed to the Permissions Department, University Science Books. Library o f Congress Cataloging-in-Publica tion Data An slyn, Eric V., 1960Modern physical organic chemistry I Eric V. Anslyn, Dennis A. Dougherty. p. em . In cludes bibliographi cal references and index. ISBN 978-1-891389-31-3 (alk. paper) 1. C hem istry, Ph ysica l organic. I. Dou gher ty, Dennis A., 1952- II. Title. 2004 547' .13-d c22 2004049617 Printed in the United States of America 10 9 8 7 6 5 4 Abbreviated Contents PART I: Molecular Structure and Thermodynamics 1. 2. 3. 4. 5. 6. CHAPTER PART Introduction to Structure and Models of Bonding 3 Strain and Stability 65 Solutions and Non-Covalent Binding Forces 145 Molecular Recognition and Supramolecular Chemistry 207 Acid-Base Chemistry 259 Stereochemistry 297 II: Reactivity, Kinetics, and Mechanisms CHAPTER PART III: CHAPTER 7. 8. 9. 10. Energy Surfaces and Kinetic Analyses 355 Experiments Related to Thermodynamics and Kinetics 421 Catalysis 489 Organic Reaction Mechanisms, Part 1: Reactions Involving Additions and / or Eliminations 537 11. Organic Reaction Mechanisms, Part 2: Substitutions at Aliphatic Centers and Thermal Isomerizations / .