tailieunhanh - Ebook Introduction to chemical engineering thermodynamics (7th edition): Part 1

Introduction to chemical engineering thermodynamics presents comprehensive coverage of the subject of thermodynamics from a chemical engineering viewpoint. This book provides a thorough exposition of the principles of thermodynamics and details their application to chemical processes. | S- CHEMICAL ENGINEERING SERIES Introduction to Chemical Engineering Thermodynamics SI VI NTH EDITION J. M. Smith . Van Ness M. M. Abbott Contents List of Symbols xi Preface xvil 1 INTRODUCTION I The Scope of Thermodynamics. 1 Dimensions and Units. 2 13 Measures of Amount or Size. 2 Force. 3 13 Temperature . 5 1A Pressure . 6 Work. 8 13 Energ . . . . . . . . 10 13 Heat. . 15 2 THE FIRST LAW AND OTHER BASIC CONCEPTS 21 Joule s Experiments. .21 22 Internal Energy. 21 23 The First Law of Thermodynamics. 22 Energy Balance for Closed Sy stems . 23 23 Thermodynamic State and Slate Functions . 26 23 Equilibrium. 29 The Phase Rule. 29 The Reversible Process. .31 Constant-V and Conslant-P Processes. .37 Enthalpy. 38 2J1 Heat Capacity . 40 Mass and Energy Balances for open Systems. 44 3 VOLUMETRIC PROPERTIES OF PURE FLUIDS 64 PVT Behavior of Pure Vĩrial Equations of State. 70 33 The Ideal Gas. 73 Application of the Vinal 33 Cubic Equations of Stale . 90 Generalized Correlations for Gases. . 99 Generalized Correlations for Liquids . 109 vii vtii 4 HEAT EFFECTS 125 44 Sensible Heat Effects - . . . 125 43 Latent Heats of Pure Substances. 133 43 Standard Heat of Reaction. 135 Standard Heal of Formation . 136 43 Standard Heat of Combustion. .139 Temperature Dependence of AW . 140 Heal Effects of industrial Reactions . 143 5 THE SECOND LAW OF THERMODYNAMICS 159 Statements of the Second Law . 160 53 Heal Engines . 161 53 Thermodynamic Temperature Scales . 163 Entropy. . 167 53 Entropy Changes of an Ideal Gas. 170 Mathematical Statement of the Second Law. . 173 Entropy Balance for open Systems. 176 Calculation of Ideal Work. 181 LostWork. . . 183 The Third Law of Thermodynamics . 188 Entropy from the Microscopic Viewpoint. 188 6 THERMODYNAMIC PROPERTIES OF FLUIDS 199 Property Relations for Homogeneous Phases. 199 Residual Properties 208