tailieunhanh - Study on change of color and some properties of high density polyethylene/organo-modified calcium carbonate composites exposed naturally at Dong Hoi - Quang Binh

This paper presents the study on the UV-Vis spectra, change of color and some properties of high density polyethylene/organo-modified calcium carbonate (HDPE/m-CaCO3) composites exposed naturally in Dong Hoi district, Quang Binh province (Vietnam). From June 2014 to June 2016, the samples of HDPE/m-CaCO3 composites were tested naturally on outdoor shelves at Dong Hoi sea atmosphere region (at Dong Hoi, Quang Binh). The change of UVVIS spectra, color and some properties of the HDPE/m-CaCO3 composites depend on geographic, weather and climatic factors (solar radiation, temperature, humidity, etc.). | Vietnam Journal of Chemistry, International Edition, 55(4): 417-423, 2017 DOI: Study on change of color and some properties of high density polyethylene/organo-modified calcium carbonate composites exposed naturally at Dong Hoi - Quang Binh Le Duc Minh1, Nguyen Thuy Chinh2, Nguyen Vu Giang2, Tong Cam Le1, Dau Thi Kim Quyen1, Le Duc Giang3, Thai Hoang2* 1 Faculty of Pedagogy Natural Sciences, Ha Tinh University, 447 26/3 street, Ha Tinh, Vietnam 2 Institute for Tropical Technology, Vietnam Academy of Science and Technology 3 Faculty of Chemistry, Vinh University Received 22 January 2017; Accepted for publication 28 August 2017 Abstract This paper presents the study on the UV-Vis spectra, change of color and some properties of high density polyethylene/organo-modified calcium carbonate (HDPE/m-CaCO3) composites exposed naturally in Dong Hoi district, Quang Binh province (Vietnam). From June 2014 to June 2016, the samples of HDPE/m-CaCO3 composites were tested naturally on outdoor shelves at Dong Hoi sea atmosphere region (at Dong Hoi, Quang Binh). The change of UVVIS spectra, color and some properties of the HDPE/m-CaCO3 composites depend on geographic, weather and climatic factors (solar radiation, temperature, humidity, etc.). In the UV-VIS spectra, the band at 265 nm showed the formation of the carbonyl groups such as ketone, lactone carbonyl and aliphatic ester which were occurred in photo-degradation process of HDPE/m-CaCO3 composites. The results of color change indicated the surface of the samples of HDPE/mCaCO3 composites was lightened continuously with increasing natural exposure time and increased in total color difference value and significant loss in both redness and yellowness. a*, b* values and electrical breakdown of HDPE/m-CaCO3 composites were decreased while their l*, E, dielectric constant and dielectric loss were increased with rising natural exposure time. Dielectric constant of HDPE/m-CaCO3 composites was in .

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