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Quasielastic light scattering studies of polypeptides: evidence for chain extension in solution

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: Dynamic light scattering and viscosimetric methods were used to study polypeptides including polyleucine, poly (γ -benzyl-L-glutamate), poly (α-L-glutamic acid), and polyproline II. Chain extension showing rod-like and flexible conformations occurred in poly(γ -benzyl-L-glutamate) and polyproline II solutions as these solutions were diluted in glacial acetic acid or in a mixed solvent of acetic acid and dichloromethane. |