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A novel silver(I)-selective PVC membrane sensor and its potentiometric applications

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Silver(I)-selective sensors were prepared from a solid-state contact polyvinyl chloride (PVC) membrane. (Z)-2-(2-((3-(2-hydroxyphenyl)-5-(p-tolyl)-1H -pyrrol-2-yl)imino)-5-(p-tolyl)-2H -pyrrol-3-yl)phenol was synthesized as an ionophore molecule and embedded in the silver(I)-selective PVC membrane composition. The sensor was also successfully applied in the analysis of real water samples. In real water samples prepared by standard addition method, recoveries in the range of 82.30%–95.15% were obtained. |